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A CW complex is built by attaching q-dimensional discs to the $(q-1)$-skeleton along maps of their boundary spheres, with the closure-finite and weak-topology conditions. Write $X^q$ for its q-skeleton and $X^{-1}=\varnothing$. The cellular chain group isThe cellular boundary is the composite of the connecting map and the relative quotient map:Consecutive maps in the relevant exact sequences compose to zero, so these maps make a cellular chain complex. Equivalently, a boundary coefficient is the degree of the attaching sphere followed by collapse onto the sphere of a selected lower cell. Its cellular homology is $\ker d_q/\mathrm{im}{d}_{q+1}$. The relative groups of successive skeleta vanish off their cell dimension; their exact sequences identify this homology with singular homology, the cellular homology theorem.

For $k\ge 1$, the sphere $S^k$ has a zero-cell and a k-cell with zero boundary. The Complex projective space ${\mathbb{CP}}^n$ has one cell in each dimension $0,2,\dots ,2n$ and no odd cells, so all cellular boundaries vanish. ConsequentlyAt $k=0$, the sphere consists of two points and $H_0(S^0)={\mathbb{Z}}^2$; at $n=0$, projective space is a point.

Put $a=2n-2$ and $Z=S^a\times S^3$. Its product CW complex has cells in dimensions $0,3,a,a+3=2n+1$. For $n>3$, these positive dimensions are distinct and never consecutive, so all cellular boundaries vanish. ThusIts $2n$-skeleton is $S^a\vee S^3$. Collapsing it gives the quotientIt induces an isomorphism on top homology, with degree $+1$ after choosing the quotient orientation. Let $p:S^{2n+1}\to {\mathbb{CP}}^n$ be the Hopf fibration and set $\varphi =pq$, the Hopf projection of a product smash quotient.

On reduced homology, the collapse kills the two lower-dimensional classes, and the remaining top class maps to zero because projective space has no odd-dimensional homology. Therefore ${\varphi }_{\ast }=0$ in every reduced degree. On homotopy groups, ${\pi }_j(Z)\cong {\pi }_j(S^a)\oplus {\pi }_j(S^3)$ for $j\ge 2$, with summands induced by the two factor inclusions. Both inclusions are collapsed by $q$, so $q_{\ast }$ and hence ${\varphi }_{\ast }$ vanish on both summands. The domain is simply connected and connected, which also handles the lower groups.

It remains to prove that $\varphi$ is not null-homotopic. The Hopf fibration has fibre $S^1$ and has the homotopy lifting property for the CW domain $Z$: a homotopy downstairs and a lift of its initial map have a lift with that specified initial value. If $\varphi$ were homotopic to a constant, lift this homotopy starting at $q$. The ending map would land in the single fibre $S^1$. Every map $Z\to S^1$ is null-homotopic, since the simply connected domain permits its lift to the contractible universal cover $\mathbb{R}\to S^1$. Thus $q$ would be null-homotopic in $S^{2n+1}$, contradicting its nonzero top homology map. Hence