Angular momentum ladder operator Created 2026-09-24 Updated 2026-10-03
The operators satisfy
They therefore change the magnetic quantum number by while preserving the total angular-momentum quantum number .
Angular momentum ladder variable Created 2026-09-24 Updated 2026-09-29
The coordinate combinations have eigenvalues , so their powers carry magnetic quantum numbers .
In atomic units the Time-independent Schrodinger equation is
The displayed equation is the Radial Schrodinger equation for the hydrogen atom. Its radial derivative terms come from the Laplacian in spherical coordinates, the Coulomb term is the potential , and separation into spherical harmonics uses the orbital angular momentum eigenvalue , producing the centrifugal term .
For , substitute . Dividing the equation by and comparing powers of gives
The solution regular at the origin has , and when both equations agree. This is the circular Coulomb bound state. Thus
The radial probability measure is . With and the Gamma integral, the mean radius of a circular Coulomb bound state is
At fixed principal quantum number , the allowed orbital angular momentum quantum numbers are , and each has magnetic quantum number . Hence the orbital quantum degeneracy is
Including electron spin would double this to , but spin is absent from the stated wavefunctions.
The canonical commutation relations are and . Substitution into the definitions of the creation and annihilation operators gives
The normalized ground state is defined by
Repeated use of gives the Cartesian number state of the three-dimensional isotropic harmonic oscillator
with energy eigenvalue
Inverting the ladder-operator definitions yields
The antisymmetry of the Levi-Civita symbol then cancels the two-creation and two-annihilation terms in , leaving the orbital angular momentum in oscillator ladder operators
Write . Then
Since the orbital angular momentum eigenvalue is , every first-excited state has
Finally,
Therefore the normalized magnetic quantum number state can be chosen as
which obeys and .
Spin lowering operator 2026-10-03
The spin lowering operator decreases the magnetic quantum number by one and annihilates the minimal-weight state.
Spin raising operator 2026-10-03
The spin raising operator increases the magnetic quantum number by one and annihilates the maximal-weight state.