Methyl abstraction 2026-10-20
Methyl abstraction transfers a metal-bound methyl group to an electrophile. A trityl cation can convert a neutral metallocene dimethyl into a cationic monomethyl, forming and opening a site for an alkene ligand.
Past exam of the chemistry B course of the University of Cambridge 2024 Paper 2 B8 b ii Solution 2026-10-20
The trityl cation acts as an electrophile and removes one metal-bound methyl by methyl abstraction. The balanced conversion isThus and , 1,1,1-triphenylethane. Transfer is formally of to carbon, not transfer of a hydride or a methyl radical. zirconium remains Zr(IV), . Ionic electron counting changes from in the dimethyl to at the cation, creating an accessible coordination site. The borate is a weakly coordinating anion, although ion pairing can still occur in solution.