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The intrinsic parity $\eta$ of a particle is the parity eigenvalue of its one-particle state at rest:For the particles in this question, $\eta =\pm 1$. A two-particle state has multiparticle parity ${\eta }_1{\eta }_2(-1{)}^{\ell }$, where $\ell$ is its relative orbital angular momentum.

The pionic-deuterium ground state has atomic $\ell =0$. Since the pion has spin zero, its total angular momentum is therefore the deuteron spin, $J=1$, and its parity is ${\eta }_d{\eta }_{\pi }={\eta }_{\pi }$. The two neutrons are identical fermions. Their antisymmetric spin-one-half singlet state would require even orbital $\ell$, but $S=0$ and $J=1$ would instead require $\ell =1$. Hence they must occupy the symmetric spin-one-half triplet state, so the orbital state is antisymmetric and $\ell$ is odd. The addition of angular momentum with $S=J=1$ permits $\ell =0,1,2$, leaving $\ell =1$. Thus parity conservation givesso the pion has intrinsic parity $\boxed{{\eta }_{\pi }=-1}$.

In ${\Delta }^{-}\to {\pi }^{-}+n$, the final total spin is $S=1/2$. Coupling it to $\ell$ to obtain $J=3/2$ givesso the allowed orbital angular momenta are $\boxed{\ell =1,2}$. The observed angular probability is ${\cos }^2\theta =|P_1(\cos \theta ){|}^2$, where $P_1$ is a Legendre polynomial; it therefore selects the $\ell =1$ partial wave rather than $\ell =2$. The parity selection rule for a two-body decay now givesTherefore the delta particle has intrinsic parity $\boxed{{\eta }_{{\Delta }^{-}}=+1}$.