For a quantum state that is an eigenstate of the parity operator, parity is its eigenvalue or . In a scalar position representation in quantum mechanics, the parity operator acts by . Since , these are its only possible eigenvalues: even wavefunctions have parity and odd wavefunctions have parity .
If the Hamiltonian commutes with the parity operator, its energy eigenstates can be chosen to have definite parity. In the quantum harmonic oscillator, parity alternates as . This helps establish selection rules: the position operator is odd under spatial reflection, so its matrix element between two states of the same parity vanishes.
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