An additive-looking energy expression does not by itself establish two noninteracting subsystems. Their allowed microstates must also form a Cartesian product of independently available states. Here the second label's allowed values depend on the first. The four allowed pairs and their energies areThe canonical partition function, with , is thereforeThe conditional sum over is and depends on ; it cannot be pulled out as the partition function of an independent second subsystem. Summing independently over and all four values would invent four forbidden pairs and give eight states instead of four.
One can make the state labels independent by writing , but then contains a coupling between them. For genuinely additive independent energies, the difference between the and states would be independent of ; here it is . Hence the proposed and subsystems cannot be treated as noninteracting independent subsystems. The literal two-value reading of the PDF's endpoint notation has been used. If that notation were instead intended as shorthand for full angular-momentum multiplets, including every integer between the endpoints, the eight allowed states would giveThe conclusion about the failure of independent-subsystem factorization is unchanged. The two state-counting conventions should not be mixed.