Let be rotation about the third axis, so invariance means . At , its diagonal signs are ; each mixed entry changes sign and must vanish.
For the remaining planar block , the quarter-turn gives
Hence and . Writing the constants as gives
Conversely, commutes with every planar rotation, so every displayed matrix is invariant under every rotation about the axis. This is an oriented-axis invariant Cartesian tensor. Symmetry was not assumed, so the antisymmetric parameter need not vanish.