In the plane wave basis of a ring, has matrix elements . Near , degenerate perturbation theory on gives
up to corrections from remote states. Thus the avoided crossing gap is to first order when .
For , a parabolic approximation about a potential minimum instead gives a local quantum harmonic oscillator spacing . A local gauge transformation removes the flux from this approximation. Actual ring levels retain exponentially small flux dependence through quantum tunnelling, while nonquadratic corrections to their mean energies are algebraic in .
For the magnetic flux spectrum of a quantum ring, the periodic boundary condition permits the normalized plane waves , with . Their energy eigenvalues are
Shifting by an integer relabels , so the ordered energy levels have period one in , or in . For , the lowest two are
extended periodically. The lowest branches cross at every half-integer , with energy . At integer , the first excited energy level has multiplicity two. The corresponding magnetic flux period is the electron magnetic flux quantum .
Figure 1.
Two lowest ring energies from free motion to a deep cosine potential
. Original calculations in a plane wave basis. From left to right: the free spectrum, a weak cosine potential with , and a deep potential with . The middle panel shows an avoided crossing at half-integer ; the deep-potential branches are almost horizontal and well separated. The dashed levels in the final panel are the parabolic approximation, whose leading anharmonic errors are visible at this finite depth. Details.
Put . Changing the sign of translates the potential by without changing its energy eigenvalues, so take a minimum at and expand there. The parabolic approximation gives
The low-lying wavefunctions are localized well inside one period. A local gauge transformation removes from their quantum harmonic oscillator equation, giving
Consequently,
The sketch consists of two nearly horizontal branches, separated by this gap, as in the right panel above. The parabolic approximation makes them completely independent of magnetic flux; in the actual ring they retain exponentially small periodic dependence through quantum tunnelling around the ring. Corrections from the nonquadratic part of the potential shift the mean energies and gap by relative order , whereas the tunnelling dependence is smaller than every power of that parameter.
In a cross-section normal to the cylinder axes, measure from the line of contact. The two circular boundaries have the parabolic approximation
for their separation. The contact point of the meniscus is at , so the leading cross-sectional area is
The area of the small meniscus cap is and is lower order. At its upper end the gap has width . A tangent semicircle therefore has radius and curvature
The Young–Laplace equation makes the liquid pressure, relative to the nearly uniform gas pressure,
At a fixed , lubrication theory gives a planar Poiseuille flow through a gap of width , with axial flux per unit
Integrating across the cusp,
The continuity equation now gives
Set . Since , this is the porous medium equation
Conservation of the fixed volume
and dimensional analysis give the self-similar solution . One integration of the resulting ordinary differential equation yields the compactly supported Barenblatt solution
Equivalently,
Its tip is . Using
in the volume constraint gives . Therefore
For vertical cylinders at equilibrium, hydrostatic pressure gives . Balancing this with the capillary pressure gives the large-height profile