The electric polarization is electric dipole moment per unit volume. It produces
The electric displacement field is useful because
so it separates free charge from the bound charge represented by . In a linear isotropic dielectric, .
Spherical symmetry and Gauss's law for give, on both sides of the interface,
Thus
With pointing from medium one to medium two, the net bound sheet charge at is the polarization jump
If one assigns surface charge separately to the inner body and outer medium, their contributions are and ; their sum is the displayed physical interface charge.

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