Assume the material gas is monatomic. Its specific enthalpy together with the radiation enthalpy is
At constant total pressure, logarithmic differentiation of
gives
Consequently the specific heat capacity at constant pressure is
The three stellar adiabatic exponents are defined by
For the gas-radiation mixture,
and
It follows that
Their defining derivatives imply the identity
For any equation of state,
Eliminating gives the requested ratio of specific heats:
In the gas-pressure limit , the mixture becomes a monatomic ideal gas, so
In the radiation-pressure limit ,
whereas and therefore
The divergence reflects the singular constant-pressure heat capacity of pure radiation: its pressure fixes its temperature independently of density.

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