Assume the material gas is monatomic. Its specific enthalpy together with the radiation enthalpy isAt constant total pressure, logarithmic differentiation of
givesConsequently the specific heat capacity at constant pressure is
givesConsequently the specific heat capacity at constant pressure is
The three stellar adiabatic exponents are defined byFor the gas-radiation mixture,andIt follows thatTheir defining derivatives imply the identity
In the gas-pressure limit , the mixture becomes a monatomic ideal gas, soIn the radiation-pressure limit ,whereas and thereforeThe divergence reflects the singular constant-pressure heat capacity of pure radiation: its pressure fixes its temperature independently of density.
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