For a binary fluid mixture, the scalar compositional order parameter may be taken as the local concentration difference between its two molecular species. Its spatial integral is fixed by their separately fixed total amounts:Locally, can change only through transport and therefore obeys a continuity equation. By contrast, is the local polar order parameter measuring the mean tail-to-head orientation of the surfactant molecules. Individual molecules can rotate in place, so the integral of need not be conserved.
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