With ,For , both branches are locally convex at the origin. Atthe negative-side curvature vanishes; for the interval near has , so a homogeneous composition there is unstable and the equilibrium free energy is its convex envelope. The sketch therefore has an ordinary upward quartic on the positive side and, beyond , a negative-curvature shoulder and a minimum on the negative side.
Articles by others on the same topic
There are currently no matching articles.