The transverse and longitudinal Péclet numbers areThe Taylor dispersion regime requires transverse diffusion to act within a longitudinal advection time,while longitudinal molecular diffusion is slow on that advection time,Together,
The advection-diffusion equation isWritewhere the bar is the cross-gap average. In the long, late-time Taylor regime, adjusts rapidly across the gap while varies slowly along the cell. The leading fluctuation balance isIts scaling isThis final inequality is precisely the transverse-equilibration condition from part i.
Put . The balance and reflecting boundary conditions giveIntegration yieldsAveraging the full transport equation givesNowbecause and . Thus the flow-induced Taylor dispersion coefficient and total effective diffusivity are
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