The transverse and longitudinal Péclet numbers are
The Taylor dispersion regime requires transverse diffusion to act within a longitudinal advection time,
while longitudinal molecular diffusion is slow on that advection time,
Together,
The advection-diffusion equation is
Write
where the bar is the cross-gap average. In the long, late-time Taylor regime, adjusts rapidly across the gap while varies slowly along the cell. The leading fluctuation balance is
Its scaling is
This final inequality is precisely the transverse-equilibration condition from part i.
Put . The balance and reflecting boundary conditions give
Integration yields
Averaging the full transport equation gives
Now
because and . Thus the flow-induced Taylor dispersion coefficient and total effective diffusivity are

Articles by others on the same topic (0)

There are currently no matching articles.