For an inextensible planar filament, . The bending energy and compressive-force potential areThe straight state has . Free pivoting means zero end moment,The endpoints sharing the axis impose ; near the straight state this removes the constant angular mode. The Neumann eigenfunctions therefore give
For , expansion through fourth order giveswhereStationarity givesThe two signs of are the symmetry-related buckled states of a supercritical pitchfork bifurcation.
The quadratic energy isEach mode is a centered Gaussian, soThe variance diverges as because the first bending mode becomes soft; Gaussian theory then fails and the quartic term controls the fluctuations.
At zero force,With the common persistence length convention ,Thermal bending therefore shortens the mean projected length even without compression. Under the strictly planar tangent-correlation convention , the same result is .
In the single-mode approximation writeFor the reference energy ,Up to an irrelevant constant from subtracting , the variational free energy isMinimization givesso the positive optimum is
The compression estimate through quartic order isUsing and ,This is finite and smooth at , unlike the zero-temperature branch point. The width of the thermal rounding of a buckling transition is controlled by the dimensionless flexibility and vanishes for an increasingly stiff or cold filament.
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