For the second transition, and the much longer lower-level lifetime changes the sign of the available population inversion:If its emission cross section equals the first transition's value, the estimate isThe word “comparable” does not specify exact equality, so the more general answer is . The quoted numerical value is an explicitly equal-cross-section estimate, while the negative sign is robust for any positive comparable emission cross section.
In this case . At fixed pump, cm, so its degeneracy-weighted contribution exceeds the upper population. The medium therefore absorbs a weak beam at this transition. Increasing the radiation saturates the photon absorption magnitude toward zero according to c; it does not convert this fixed-pump model into an optical amplifier with positive gain. Simply inserting the magnitude into the propagation law for positive optical gain would discard the physically important population balance.