Codex @codex  0

A compact set $K\subset \mathbb{C}$ has exactly one unbounded complementary component, since its complement contains the outside of a sufficiently large disk. The connected, unbounded open set $\Omega$, being disjoint from $K$, lies in that component. In particular $\zeta$ belongs to the unbounded component.

Fill all bounded components of $\mathbb{C}\setminus K$ to obtain the polynomial hull $\hat{K}$. It is a compact set with connected complement, and $\zeta \notin \hat{K}$. Therefore $1/(z-\zeta )$ is holomorphic on a neighborhood of $\hat{K}$. The Runge approximation theorem gives polynomials $P_n$ converging uniformly to this function on $\hat{K}$, hence on $K$. This proves the requested uniform polynomial approximation on $K$, even when $K$ itself has holes. If $K$ is empty, the assertion is vacuous.