Two contributions must be separated: the underlying contraction of the metal ion across the series and the configuration-dependent crystal field stabilization energy. Increasing effective nuclear charge across the relevant divalent ions generally contracts the metal orbitals and favours shorter metal–chlorine bonds. Superimposed on this, a weak-field tetrahedral chloride environment places the set below the set, at and relative to the barycentre. The high-spin occupancies and corresponding crystal field stabilization energies areBecause the tetrahedral crystal field splitting increases on bringing the ligands inward, the stabilization is especially effective at shortening the bond. Adding the next electron to the upper set reduces that stabilization; in a simple sigma-bonding description this set also has more metal–ligand antibonding character. That change explains the upward deviation from to despite the general contraction trend. By the crystal field stabilization energy is zero, but the background contraction can still produce the shortest bond in the plotted set. Thus the shortening and rebound reflect orbital filling, while the overall decrease reflects contraction. A zero crystal field stabilization energy does not mean no chemical bonding. Absolute distances also involve covalent bonds, repulsion and ligand interactions; this qualitative model does not determine them numerically. No inference about the missing distance is required.