A tricritical point joins continuous and first-order transition loci and requires tuning an additional temperature-independent control. In the scalar sextic potential
it occurs at : both the quadratic and quartic terms vanish. At , the transition is continuous at ; at , it is first-order at . The jump tends to zero as , so these loci meet at the tricritical point.
For the three-control phase diagram with coordinates , the sheet below these transition loci has coexistence of the two ordered phases. For its boundary is the ordinary continuous critical line . For the boundary is a tricritical three-phase line, where and all coexist. Two symmetry-related tricritical wings extend from that line into and , describing first-order coexistence between small- and large-magnitude phases of the same sign. Each wing ends along an ordinary wing critical edge.
The critical-edge conditions give
Here , so these are ordinary quartic endpoints. The two wing critical edges and the zero-field ordinary critical line are three continuous critical lines meeting at the tricritical point; the three-phase first-order line also ends there. The “3D” phase diagram refers to three independent controls; it is distinct from the spatial dimension of the field theory.
The figure uses actual sextic-potential coexistence surfaces rather than drawing arbitrary wings. For two coexisting nonnegative minima , put . The tricritical wing coexistence factorization
holds when , and . It proves that both minima are globally stable. The limits and produce the three-phase line and critical edge, respectively; reflection gives the other wing.
Figure 1.
Scalar tricritical coexistence wings and the zero-field phase diagram
.
At , on the ordered side and . At the critical isotherm . Thus the tricritical mean-field critical exponents are
The source's extra control is required to tune to zero; simply changing temperature in a generic quartic system does not produce tricriticality. The tricritical upper critical dimension is three, as established in Question 3.
For with , the displayed line has three global minima, and . The factorization proves their coexistence. Two nonzero-field tricritical wings and the zero-field ordered coexistence sheet meet along this line. Its order-parameter discontinuity tends to zero as it terminates at the tricritical point.
For with , the ordinary critical edge of a tricritical wing satisfies . For , , and . Its fourth derivative is . The two signs of give the two wings.