The Dirichlet uniqueness for the Poisson equation follows from a positive integral. Suppose satisfy the same data, and put . Then is a harmonic function in and vanishes on . Green's first identity, applied with both arguments , gives
Thus , and is constant on the connected body. Its zero boundary value makes that constant zero. This proves at most one temperature field; it does not require an independent existence construction. As usual, the argument assumes a bounded body and sufficient regularity for Green's first identity, or the corresponding finite-energy weak formulation.
For the composite body, let and be the differences in and . They are harmonic functions, have a common interface value , and obey
The unit normal vector points out of ; the outward normal of on its inner boundary is . Keeping that sign in Green's first identity gives
The outer boundary term in is zero. Weight these equations by the positive coefficients that match the flux condition:
Both Dirichlet energies must vanish. Hence both differences are constants; the outer data set the constant in to zero, and interface continuity sets the constant in to zero. This establishes uniqueness for a harmonic transmission problem. Physically and play the roles of the inner and outer thermal conductivities; continuity of temperature and normal heat flux is what cancels the interface contribution.