The trityl cation acts as an electrophile and removes one metal-bound methyl by methyl abstraction. The balanced conversion is
Thus and , 1,1,1-triphenylethane. Transfer is formally of to carbon, not transfer of a hydride or a methyl radical. zirconium remains Zr(IV), . Ionic electron counting changes from in the dimethyl to at the cation, creating an accessible coordination site. The borate is a weakly coordinating anion, although ion pairing can still occur in solution.
Weakly coordinating anion 2026-10-20
A weakly coordinating anion balances charge while binding only weakly to the cationic reaction center. Delocalized charge, low basicity and steric shielding can leave a metal coordination site accessible. Weak coordination is relative, not an assertion that ion pairing is absent.