Reaction of organic anions. Part 108. On the mechanism of the vicarious nucleophilic substitution of hydrogen in nitroarenes by Mieczysław Mąkosza and Tomasz Glinka 2026-10-20
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Journal of Organic Chemistry 48, 3860–3861. Isotope/base-rate effects and hydrogen-versus-halogen substitution competitions support reversible sigma-H addition and base-induced elimination, excluding the proposed hydride-shift alternative.
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