Madelung energy ordering rule
ID: madelung-energy-ordering-rule
Looking at the energy level of the Schrödinger equation solution for the hydrogen atom, you would guess that for multi-electron atoms that only the principal quantum number would matter, azimuthal quantum number getting filled randomly.
However, orbitals energies for large atoms don't increase in energy like those of hydrogen due to electron-electron interactions.
In particular, the following would not be naively expected:
This rule is only an approximation, there exist exceptions to the Madelung energy ordering rule.
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