I think they are a tool to calculate the probability of different types of particle decays and particle collision outcomes. TODO Minimal example of that.
And they can be derived from a more complete quantum electrodynamics formulation via perturbation theory.
At Richard Feynman Quantum Electrodynamics Lecture at University of Auckland (1979), an intuitive explanation of them in termes of sum of products of propagators is given.
- www.youtube.com/watch?v=fG52mXN-uWI The Secrets of Feynman Diagrams | Space Time by PBS Space Time (2017)
Initially a phenomenological guess to explain the periodic table. Later it was apparently proven properly with the spin-statistics theorem, physics.stackexchange.com/questions/360140/theoretical-proof-of-paulis-exclusion-principle.
And it was understood more and more that basically this is what prevents solids from collapsing into a single nucleus, not electrical repulsion: electron degeneracy pressure!
Bibliography:
- www.youtube.com/watch?v=EK_6OzZAh5k How Electron Spin Makes Matter Possible by PBS Space Time (2021)