Enantiomer self-disproportionation is a phenomenon observed in asymmetric reactions where a racemic mixture (a 1:1 mixture of two enantiomers) separates into two fractions that have differing concentrations of the enantiomers. In simpler terms, it describes a process in which two enantiomers in a mixture can separate such that one of the enantiomers is more prevalent in one portion of the mixture than in the other.

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