The Gibbs rotational ensemble is a statistical mechanical ensemble used to describe the behavior of systems where rotation plays a significant role, such as gases of rigid rotors or polyatomic molecules. This ensemble is particularly useful for understanding the distribution of molecular orientations in a given system at thermal equilibrium. In statistical mechanics, ensembles represent different ways to count the states of a system based on varying conditions. The Gibbs ensemble specifically refers to a combination of both rotational and translational degrees of freedom in molecules.
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