A supporting electrolyte, also known as a background electrolyte, is a substance added to an electrochemical system to provide a stable ionic environment, which enhances the conductivity of the solution. It helps maintain a constant ionic strength and can mitigate potential variations in the charge distribution during electrochemical reactions.
Sulfide stress cracking (SSC) is a type of environmental cracking that occurs in metals, particularly in high-strength steel alloys, when they are exposed to a sulfide-containing environment under tensile stress. This phenomenon is of particular concern in industries such as oil and gas, petrochemicals, and other applications involving sour environments, where hydrogen sulfide (H₂S) is present.
A strong electrolyte is a substance that fully dissociates into ions when dissolved in water. This means that in solution, it exists entirely as individual ions rather than as intact molecules. Strong electrolytes typically include: 1. **Strong Acids**: These are acids that completely ionize in solution. Examples include hydrochloric acid (HCl), sulfuric acid (H₂SO₄), and nitric acid (HNO₃).
The Severinghaus electrode is a type of electrochemical sensor used for measuring partial pressure of carbon dioxide (pCO2) in various applications, particularly in medical and environmental monitoring. This electrode is notable for its ability to provide accurate and continuous measurements of CO2 levels. The Severinghaus electrode consists of a pH-sensitive glass membrane that is in contact with an electrolyte solution.
A salt bridge is a crucial component in electrochemical cells, particularly in galvanic (voltaic) cells and electrolytic cells. It serves several important functions: 1. **Complete the Circuit**: The salt bridge connects the two half-cells of an electrochemical cell, allowing the flow of ions. This completes the electrical circuit necessary for the cell to function.
Sacrificial metal refers to a type of metal that is intentionally used in a protective capacity to prevent corrosion in other metals, primarily through a process called galvanic protection or cathodic protection. This technique is commonly used in various applications, including the protection of pipelines, tanks, and marine structures. In this context, a sacrificial anode (often made of zinc, magnesium, or aluminum) is attached to a metal structure (such as steel) that needs protection from corrosion.
Ruthenium-iridium nanosized coral refers to a type of nanomaterial that combines ruthenium (Ru) and iridium (Ir) in a coral-like structure at the nanoscale. These materials are often explored for various applications due to their unique properties. 1. **Composition**: Ruthenium and iridium are both transition metals in the platinum group, known for their catalytic, electronic, and magnetic properties.
"Rusticle" generally refers to a type of rust or corrosion that forms on metals, particularly in marine environments. In this context, it is often associated with the buildup of iron oxide and other corrosion products on shipwrecks or submerged structures, creating an appearance similar to stalactites or icicles made of rust. Rusticles can result from the biological processes of microorganisms, particularly certain types of bacteria that thrive in oxygen-poor environments, as they metabolize and interact with the metals.
Rouging is a process used primarily in the semiconductor and pharmaceutical industries, as well as in cleanroom environments, to describe the formation of reddish-brown stains or films on surfaces, typically metals, due to the oxidation of iron or other transition metals. These stains can occur in various types of equipment and environments, where metals are exposed to moist air, resulting in corrosion.
Reversible charge injection limit, often abbreviated as RCIL, is a term used in the context of semiconductor devices, particularly organic light-emitting diodes (OLEDs) and organic photovoltaics (OPVs). It refers to the maximum amount of electrical charge that can be injected into a material or device without causing permanent changes to its properties. In simpler terms, it defines the threshold up to which charge carriers (electrons and holes) can be introduced into a system in a reversible manner.
The term "red plague" refers to a form of corrosion that affects galvanized steel, particularly in the context of various industrial applications. It is commonly associated with the deterioration of the protective zinc coating on steel, leading to rust and corrosion of the underlying metal. This phenomenon can arise from factors such as exposure to moisture, contaminants, and certain environmental conditions.
The Randles–Sevcik equation is a fundamental relationship in electrochemistry that describes the current response of a redox-active species undergoing a diffusion-controlled process during a cyclic voltammetry experiment. It relates the peak current (\(I_p\)) measured during the voltammetric scan to various parameters, including the concentration of the active species, the scan rate, and the diffusion coefficient.
The Quinhydrone electrode is a type of redox electrode that is used primarily in electrochemistry to measure the potential of a half-cell reaction involving quinone and hydroquinone. The electrode is composed of a mixture of quinone (an oxidized form) and hydroquinone (the reduced form), which can be used to establish a reference potential in aqueous solutions.
A proton conductor is a material that allows protons (H⁺ ions) to move through it with high ionic conductivity. In the context of electrochemistry and fuel cell technology, proton conductors are crucial because they facilitate the transport of protons from the anode to the cathode, enabling the conversion of chemical energy into electrical energy.
A potentiometric sensor is a type of sensor used to measure the voltage (potential) in a system, primarily for determining the concentration of a specific ion or chemical species in a solution. These sensors operate on the principle of measuring the electric potential difference between two electrodes that interact with the target ions in a solution.
A potassium selective electrode (KSE) is a type of ion-selective electrode specifically designed to measure the concentration of potassium ions (K⁺) in solution. These electrodes are widely used in various fields, including clinical diagnostics, environmental monitoring, and food testing. ### Key Features of Potassium Selective Electrodes: 1. **Working Principle**: The potassium selective electrode operates based on the Nernst equation, which relates the electrode potential to the concentration of ions in solution.
In electrochemistry, polarization refers to the phenomenon where the potential of an electrode changes from its equilibrium value due to various factors during an electrochemical reaction. This change in potential occurs when an electrode is subjected to an external current or when the reaction kinetics are not favorable, leading to a deviation from the expected behavior.
Plasma electrochemistry is an interdisciplinary field that combines the principles of plasma physics and electrochemistry to explore and develop new processes and materials for various applications. Plasma refers to an ionized gas that contains a significant number of charged particles, while electrochemistry involves the study of chemical reactions that involve the transfer of electrons, typically at the interface of an electrode and an electrolyte. In plasma electrochemistry, plasma is used to modify surfaces, synthesize materials, or facilitate electrochemical reactions.
The Pitting Resistance Equivalent Number (PREN) is a numerical value used to assess the resistance of stainless steel and other alloys to pitting corrosion, particularly in environments that are chloride-rich, such as marine settings. Pitting corrosion is localized corrosion that leads to the formation of small holes or pits in the metal. PREN is calculated using the formula: \[ \text{PREN} = %Cr + 3.
Piping corrosion circuit refers to the phenomenon where electrochemical corrosion occurs in piping systems due to the presence of electrical circuits formed by corrosion cells. These can significantly affect the integrity and lifespan of piping materials used in various industries, including oil and gas, chemical processing, and water treatment. Here are some key points about piping corrosion circuits: 1. **Corrosion Process**: Corrosion in piping systems is an electrochemical process that typically involves an anode and a cathode.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 5. . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact