Fine structure by Ciro Santilli 40 Updated 2025-07-16
Split in energy levels due to interaction between electron up or down spin and the electron orbitals.
Numerically explained by the Dirac equation when solving it for the hydrogen atom, and it is one of the main triumphs of the theory.
Zeeman effect by Ciro Santilli 40 Updated 2025-07-16
Split in the spectral line when a magnetic field is applied.
Non-anomalous: number of splits matches predictions of the Schrödinger equation about the number of possible states with a given angular momentum. TODO does it make numerical predictions?
www.pas.rochester.edu/~blackman/ast104/zeeman-split.html contains the hello world that everyone should know: 2p splits into 3 energy levels, so you see 3 spectral lines from 1s to 2p rather than just one.
p splits into 3, d into 5, f into 7 and so on, i.e. one for each possible azimuthal quantum number.
It also mentions that polarization effects become visible from this: each line is polarized in a different way. TODO more details as in an experiment to observe this.
Video 1.
Experimental physics - IV: 22 - Zeeman effect by Lehrportal Uni Gottingen (2020)
Source.
This one is decent. Uses a cadmium lamp and an etalon on an optical table. They see a more or less clear 3-split in a circular interference pattern,
They filter out all but the transition of interest.
Video 2. Source. Does not appear to achieve a crystal clear split unfortunately.
Light cone by Ciro Santilli 40 Updated 2025-07-16
The key insights that it gives are:
  • future and past are well defined: every reference frame sees your future in your future cone, and your past in your past cone
    Otherwise causality could be violated, and then things would go really bad, you could tell your past self to tell your past self to tell your past self to do something.
    You can only affect the outcome of events in your future cone, and you can only be affected by events in your past cone. You can't travel fast enough to affect.
    Two spacetime events with such fixed causality are called timelike-separated events.
  • every other event (to right and left, known as spacelike-separated events) can be measured to happen before or after your current spacetime event by different observers.
    But that does not violate causality, because you just can't reach those spacetime points anyways to affect them.
Figure 1.
Animation showing how space-separated events can be observed to happen in different orders by observers in different frames of reference
. Source.
We select for the general Equation "Schrodinger equation":
giving the full explicit partial differential equation:
Equation 1.
Schrödinger equation for a one dimensional particle
.
The corresponding time-independent Schrödinger equation for this equation is:
Then, for each energy , from the discussion at Section "Solving the Schrodinger equation with the time-independent Schrödinger equation", the solution is:
Therefore, we see that the solution is made up of infinitely many plane wave functions.
Now, there are two ways to go about this.
The first is the stupid "here's a guess" + "hey this family of solutions forms a complete basis"! This is exactly how we solved the problem at Section "Solving partial differential equations with the Fourier series", except that now the complete basis are the Hermite functions.
The second is the much celebrated ladder operator method.
Quantum tunnelling by Ciro Santilli 40 Updated 2025-07-16
Examples:
Is the only atom that has a closed form solution, which allows for very good predictions, and gives awesome intuition about the orbitals in general.
It is arguably the most important solution of the Schrodinger equation.
In particular, it predicts:
The explicit solution can be written in terms of spherical harmonics.
Video 1.
A Better Way To Picture Atoms by minutephysics (2021)
Source. Renderings based on the exact Schrödinger equation solution for the hydrogen atom that depict wave function concentration by concentration of small balls, and angular momentum by how fast the balls rotate at each point. Mentions that the approach is inspired by de Broglie-Bohm theory.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
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