 Constitutional supercooling

Constitutional supercooling occurs when liquid ahead of a solidification phase boundary lies below its local liquidus. In a saline liquid with $T_L=-mC$ and $m>0$, salt rejection enriches the interface liquid and depresses its liquidus; as the concentration decreases away from the interface, the liquidus rises. If it rises faster than the actual temperature, a supercooled interval appears. This can make a planar solidification phase boundary unstable.