Constrained order-parameter free energy
ID: constrained-order-parameter-free-energy
Fix the spatial mean of a scalar order parameter to and sum the Boltzmann weights of all configurations with that mean. The resulting constrained partition function defines this free-energy density, with an additive normalization fixed consistently. For an applied conjugate field , , up to the chosen measure normalization. The thermodynamic limit gives . A homogeneous Landau free energy is an approximation to this constrained potential; phase-separated configurations can convexify it in the full thermodynamic limit.
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