Cyclization in step-growth polymerization

ID: cyclization-in-step-growth-polymerization

In cyclization in step-growth polymerization, compatible functional groups on the same chain react and close it into a ring. They consume groups without merging two molecules. If ring-closing events and intermolecular joins occur in an otherwise balanced bifunctional feed, the group conversion is , while . Thus
For example, an dimer can close its remaining and ends: two group pairings have occurred among two starting monomer molecules, giving , but the resulting single cyclic molecule has only two monomeric units. This counterexample shows exactly where the linear Carothers equation fails. Rings have no chain ends, so counting every chain-bearing molecule as two ends also fails.

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