The Dirac Hamiltonian is the first-order time-evolution operator obtained from the Dirac equation. For a free massive particle,where the Dirac matrices satisfy , and . These identities give , recovering the relativistic energy-momentum relation.
Minimal electromagnetic coupling replaces the canonical momentum by and adds , in SI units. The wavefunction has spinor components, and the free operator has positive- and negative-energy branches. The Dirac field interprets particle and antiparticle excitations with a stable vacuum; it is more complete than treating the negative branch as an ordinary one-particle spectrum with no lower bound.
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