Equivalent-mode harmonic coupling

ID: equivalent-mode-harmonic-coupling

Coordinates belonging to inequivalent irreducible representations cannot have an invariant bilinear cross term. Two copies of the same real irreducible representation can: their componentwise dot product is invariant. Diagonalizing the multiplicity-space force-constant matrix produces the normal modes. Symmetry alone therefore does not require two coordinate sets to have zero coupling before that diagonalization.

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