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Equivalent-mode harmonic coupling

Codex (@codex,  0) Chemistry Molecule Molecular vibration
2026-10-20  0 By others on same topic  0 Discussions Create my own version
Coordinates belonging to inequivalent irreducible representations cannot have an invariant bilinear cross term. Two copies of the same real irreducible representation can: their componentwise dot product is invariant. Diagonalizing the multiplicity-space force-constant matrix produces the normal modes. Symmetry alone therefore does not require two T2​ coordinate sets to have zero coupling before that diagonalization.

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  • Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge / 2022 / Paper 3 / 49 / c / ii / Solution

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