 Exposed face of the dual ball defined by the unit

For a nonzero unital C-star algebra, a positive functional on a C-star algebra obeys $\Vert x\Vert =x(1_A)$, and conversely this equality for a bounded functional implies positivity. Therefore its state on a C-star algebra functionals are exactly the maximizers of the real linear evaluation $x\mapsto \mathrm{Re}x(1_A)$ on the closed dual unit ball. If a convex combination reaches that maximum, each constituent must reach it: each real part is at most one, and their weighted mean is one. The modulus bound then forces evaluation to equal one, so each constituent is again a state. Hence the state space is an exposed face and a face of a convex set.