A state is a positive functional of norm one. The state space is a weak-star compact convex subset of .
Write with both terms Hermitian. At least one is nonzero; its norm equals its spectral radius, so it has a nonzero spectral value. Spectral values attained by C-star states gives a state taking that nonzero value on the chosen term. Both state values on are real, so the corresponding complex value on cannot vanish. This also detects nonzero quasinilpotent elements, which cannot be separated by looking only at their own spectrum.
On the linear span of , define . Affine spectral mapping gives , making this well-defined with norm one and . A norm-preserving Hahn-Banach theorem extension to the whole C-star algebra remains unital; the norm characterization of a positive functional on a C-star algebra makes it a state on a C-star algebra attaining the spectral value.
A pure state is an extreme point of the state space. The Krein-Milman theorem guarantees pure states, and every positive element attains its norm at some pure state.

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