Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2021/paper-1/a3/b/iii/solution

The calculated rotational constant gives . At room temperature, taken as , the continuous maximum is ; comparing the adjacent integer populations gives . Taking instead gives and the same integer answer.
At , . In particular,
and , so . The integer comparison avoids treating a noninteger angular momentum quantum number as a physical state.

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