Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-2/a6/a/solution

Take the energy of an isolated, field-free gas atom as zero, and let be the field-independent binding energy at one adsorption site. The two adsorbed spin energies are
Here is the Bohr magneton. The lower state is stabilized by increasing ; the assignment of the two signs to names for the spin projections is a convention.

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