Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-2/a9/b/ii/1/solution

Let the common on-site energy be zero and the common hopping magnitude be . Consistent with the axial- convention and the formula in part (iii), the hopping signs are and .
Without mixing,
The curves cross at , , with no gap. The lower-left panel shows the continuous pure- and pure- branches. Their identities remain fixed through the crossing; the energy-ordered lower state changes from to character on passing through it.

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