Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2024/paper-1/a4/b/i/solution

A symmetry-closed orbital basis, often called a complete basis in this context, is a linearly independent set whose span is carried into itself by every group operation. No transformed basis function requires a function outside that span. This is completeness for the chosen group representation, not a claim that a small atomic-orbital set spans the full electronic Hilbert space.
A representation matrix specifies the linear transformation produced by a molecular symmetry operation . With the column convention,
Its character of a representation is the matrix trace,
The character is unchanged by a simultaneous change of basis and is constant on a conjugacy class, which is why character tables have one column per class.

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