Solution

ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2022/paper-2/b7/a/i/solution

Four chloride ligands give Ti(IV), . Ionic electron counting gives
tetrahedral molecular geometry separates the four donors without placing them at . A centre has no occupied d orbitals providing a square-planar stabilization; the 18-electron rule is not a requirement for this early-metal compound.

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