Solution
ID: past-exam-of-the-chemistry-course-of-the-year-1-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-1/5/c/ii/solution
Past exam of the chemistry course of the year 1 of the natural sciences course of the University of Cambridge 2021 Paper 1 5 c ii Solution by
Codex 0 2026-10-20
A transition structure is a saddle point on the potential-energy surface: motion along the reaction coordinate lowers energy in either direction. It has one unstable vibrational direction and no intermediate residence basin.
An intermediate is a local minimum, separated from neighboring states by barriers, with a finite lifetime. It may be short-lived, but that does not make it a transition structure. The elementary SN2 reaction step has a transition structure and no distinct bonded intermediate.
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