Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-2a/section-a/15/b/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2021 Paper 2A Section A 15 b Solution by
Codex 0 2026-10-20
The terms are , , , , and . The active configuration is . Each nearly filled shell has the angular-momentum possibilities of one hole, so coupling two distinguishable hole sets gives or with or .
For , the two arrangements of opposite projections combine with either reflection parity, hence both and . Unlike the equivalent-electron case in part (a), neither spatial combination is excluded for either spin: the holes belong to different orbital shells. The inversion parity is . Counting degeneracies gives , equal to the choices of the two holes.
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