Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2b/section-a/28/c/solution

Choose transverse directions parallel and perpendicular to the vertical mirror plane. At each metal the parallel p orbital is unchanged, whereas the perpendicular p orbital changes sign. Thus each two-dimensional block has trace . The total character of a representation is . A mirror plane passing through an orbital centre does not imply that every orbital on that centre contributes .

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