Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-3/38/b/i/solution

A Fischer carbene complex typically has a low-oxidation-state, relatively electron-rich middle/late transition metal with strong pi-acceptor ligands such as CO. The carbene is treated as a neutral two-electron donor; metal-to-carbene back-donation contributes to its bond, but its carbon remains electrophilic. An OR or NR substituent stabilizes that carbon by heteroatom donation. Here the metal is Cr(0), , in an 18-electron pentacarbonyl complex.
A Schrock carbene complex usually contains an early metal in a high oxidation state, often , with electron-donating ligands rather than a shell of pi-accepting carbonyls. Its alkylidene has substantial dianionic character in ionic counting, and its carbon is correspondingly nucleophilic. Alkyl substituents are common; heteroatom stabilization of an electrophilic carbon is not the defining feature. These are bonding/electronic limiting descriptions rather than a rule based only on the drawn metal-carbon double bond.

New to topics? Read the docs here!