Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-3/49/c/iii/solution

For a real nonmagnetic electronic triplet, the symmetric square of a group representation decomposes as
The coordinate shifts all components equally and does not remove the degeneracy. The linear Jahn-Teller selection rule therefore permits and vibrational modes to couple and split the triplet. Both methane vibrational triplets are symmetry-eligible. A nonzero allowed coupling generally produces a symmetry-lowering instability, although symmetry alone does not determine its strength or the preferred minimum.

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