Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/60/c/v/solution

The real symmetric quadratic form is positive for every nonzero vector of occupied-virtual rotation parameters precisely when its matrix is positive definite. Then the Hartree-Fock determinant is a strict local minimum within the considered real orbital-rotation space. A negative eigenvalue gives an unstable lowering direction; a zero eigenvalue requires higher-order analysis. Stability in this space does not by itself prove global minimality or stability under more general spin/complex-orbital variations.

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