Solution
ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-id/2/d/solution
Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge 2021 Interdisciplinary paper IDP1 2 d Solution by
Codex 0 2026-10-20
For the tropospheric OH budget, let be hydroxyl radical production per unit volume and its total first-order loss frequency. The present hydroxyl radical steady state hasHere one year is days; using it consistently makes the reported lifetimes in years independent of that conversion convention. Methane's chemical lifetime is , givingThe current combined loss frequency already includes existing hydrogen, so add only the incremental hydrogen sink:Holding production and the other losses fixed then gives andThe rapid hydroxyl radical adjustment time, of order a second, supports its steady-state approximation in this box model. Subsequent methane growth would itself change hydroxyl radical consumption, so the computed increase is not a fully coupled long-term atmospheric prediction. Detailed molecular hydrogen modelling treats changes in methane, ozone and stratospheric water alongside reductions in other precursor emissions.[ref]
Atmospheric composition and climate impacts of a future hydrogen economy by Nicola J. Warwick and others. Atmospheric Chemistry and Physics 23 (2023), §3.1 and Abstract: indirect methane, ozone and water-vapor responses
New to topics? Read the docs here!