Solution
ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-1/2/a/ii/solution
Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge 2022 Paper 1 2 a ii Solution by
Codex 0 2026-10-20
At high temperature, tends towards the nearly constant Curie constant of weakly correlated centers. On cooling, falls because neighboring spins increasingly correlate antiparallel. The broad maximum in marks the crossover from the high-temperature Curie-like regime to substantial short-range order.
At still lower temperature, the Magnetic susceptibility becomes small because the antiferromagnetic ladder favors a singlet-like ground state and has few thermally accessible magnetic excitations. An even-leg spin ladder can have a spin gap, which reinforces this suppression. A broad Magnetic susceptibility maximum and falling support short-range antiferromagnetic correlations; they do not establish a three-dimensional Néel transition. Such a transition would require independent evidence, rather than identifying the broad maximum itself as the ordering temperature.
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