Solution
ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2/section-e/26/a/ii/solution
Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge 2022 Paper 2 Section E 26 a ii Solution by
Codex 0 2026-10-20
At high density, disorder can frustrate efficient local packing and leave particles with very little room to move. An ordered arrangement can give every particle a larger cage of allowed displacements. The extensive gain in vibrational/configurational freedom within these cages can outweigh the loss of distinct spatial arrangements of cages. Visual order is therefore not a reliable measure of entropy. At low density the fluid's freedom to rearrange dominates, whereas sufficiently dense packing can favour a crystal through accessible free volume.
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