 Solution

Near a parabolic valence band maximum $E_v$, the missing-electron effective mass is $m_h^{\ast }>0$. The same two-dimensional state counting givesMultiplication eliminates the chemical potential, giving the semiconductor mass-action lawFor an intrinsic semiconductor, charge neutrality imposes $n=p=n_i$, soThe intrinsic chemical potential is not exactly midgap when the two effective masses differ: ${\mu }_i=(E_c+E_v)/2+(k_{B}T/2)\log (m_h^{\ast }/m_e^{\ast })$. The exponential suppression still justifies the assumed nondegenerate regime here.